Removal of benzotriazole by Photo-Fenton like process using nano zero-valent iron: Response surface methodology with a Box-Behnken design

In this paper, the removal of benzotriazole (BTA) was investigated by a Photo-Fenton process using nano zero valent iron (NZVI) and optimization by response surface methodology based on Box-Behnken method. Effect of operating parameters affecting removal efficiency such as H2O2, NZVI, and BTA concentrations as well as pH was studied. All the experiments were performed in the presence of ultraviolet radiation. Predicted levels and BTA removal were found to be in good agreement with the experimental levels (R2 = 0. 9500). The optimal parameters were determined at 60 min reaction time, 15 mg L-1 BTA, 0.10 g L-1 NZVI, and 1.5 mmol L-1 H2O2 for Photo-Fenton-like reaction. NZVI was characterized using X-ray diffraction (XRD), transmission electron microscope (TEM) images, and scanning electron microscope (SEM) analysis

Inactivation of Fecal coliforms during solar and photocatalytic disinfection by zinc oxide (ZnO) nanoparticles in compound parabolic concentrators (CPCs)

Water samples of 0, 50, and 100 nephelometric turbidity units (NTU) spiked with fecal coliforms (107 CFU/ml) were exposed to natural sunshine in 1l quartz glass tubes fitted with rectors' compound parabolic concentrators CPCS at two forms CPC1 (whit nanoparticle zinc oxide) and CPC2(without nanoparticle zinc oxide). The samples were characterized using the X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM). On clear days, the complete inactivation times (more than 7-log unit reduction in bacterial population) in the systems with CPC1, and CPC2 were 15, and 30 min, respectively. The maximum temperatures obtained in the water samples were 80°C for CPC1, and 82°C for CPC2. The use of CPC1 with hydroxyl radicals (OH·) production significantly improved the efficiency of the old CPCS technique, since these systems (CPC1-2) shortened the exposure times to solar radiation and also minimized the negative effects of turbidity and also regrowth was zero in the disinfected samples. Due to two simultaneous effects of high temperatures and UV, regrowth in most ways of solar disinfection was not seen in these examples. Overall, this technology has been proved to be a good enhancement method to inactivate microorganisms under real conditions and represents a good alternative technique to drinking water treatment. © 2019, Islamic Azad University

Spanning trees for the geometry and dynamics of compact polymers

Using a mapping of compact polymers on the Manhattan lattice to spanning trees, we calculate exactly the average number of bends at infinite temperature. We then find, in a high temperature approximation, the energy of the system as a function of bending rigidity and polymer elasticity. We identify the universal mechanism for the relaxation of compact polymers and then endow the model with physically motivated dynamics in the convenient framework of the trees. We find aging and domain coarsening after quenches in temperature. We explain the slow dynamics in terms of the geometrical interconnections between the energy and the dynamics.Comment: 10 pages, 8 figure

Heterogeneous oxidation of sulfacetamide in aquatic environment using ultrasonic and nano-fenton: Kinetics intermediates and bioassay test

In present study, degradation of sulfacetamide from a synthetic wastewater by sonofenton process using zero valent iron nanoparticles was investigated. The synthesized iron nanoparticles were characterized using transmission electron microscopy (TEM), UV-visible and X-ray diffraction pattern (XRD). The effect of various parameters, such as pH, nZVI dose, H2 O2 concentration and contact time was studied with batch experiments. The removal efficiency of sulfacetamide by US/nZVI/H2 Of process was about 91 for reaction time of 60 min, but less than 27 of chemical oxygen demand (COD) was removed. Kinetics studies showed that the degradation of sulfacetamide fitted well to the pseudo-second-order model. Using the LC/MS device, five intermediate from degradation of sulfacetamide were detected. The toxicity test, using micro toxicity study also showed that the effluent from the sono-Fenton reactor has a lower toxicity than sulfacetamide antibacterial. © 2019 Desalination Publications. All rights reserved

Generalized vegetation map of north Merrit Island based on a simplified multispectral analysis

A simplified system for classification of multispectral data was used for making a generalized map of ground features of North Merritt Island. Subclassification of vegetation within broad categories yielded promising results which led to a completely automatic method and to the production of satisfactory detailed maps. Changes in an area north of Happy Hammocks are evidently related to water relations of the soil and are not associated with the last winter freeze-damage which affected mainly the mangrove species, likely to reestablish themselves by natural processes. A supplementary investigation involving reflectance studies in the laboratory has shown that the reflectance by detached citrus leaves, of wavelengths lying between 400 microns and 700 microns, showed some variation over a period of seven days during which the leaves were kept in a laboratory atmosphere

On the feasibility of attribute-based encryption on Internet of Things devices

Attribute-based encryption (ABE) could be an effective cryptographic tool for the secure management of Internet of Things (IoT) devices, but its feasibility in the IoT has been under-investigated thus far. This article explores such feasibility for well-known IoT platforms, namely, Intel Galileo Gen 2, Intel Edison, Raspberry pi 1 model B, and Raspberry pi zero, and concludes that adopting ABE in the IoT is indeed feasible